Chad -
While this is a sport that is not for the faint of wallet, money will not make your dive safe. It will not get you out of the back of the cave when murphy hits. That being said, the best gear is the gear that you are familiar with, comfortable in, and comfortable using. We're all built differently and have slightly different variations of what is "natural" for us. By that I mean you want to be 100% comfortable with your gear at all times. If the best, most expensive piece of gear is awkward for you to use, then it is probably not right for you.
I would suggest finding an LDS that has a large inventory of gear that you can dive and try out. Get in with the shop and find an instructor. Find buddies that you get along with and see if they'll let you test dive some of their gear for a dive or two. If they're like a lot of us, they'll have more gear than they can dive in a (day, week, lifetime...) and probably won't have a problem letting you try it out and discuss the pros and cons with you before and afterwards. Look at how others configure their gear and find what is logical and natural to you.
Spend your money diving and getting the experience. Build your gear up one piece at a time after you have tried out different models from different manufacturers.
To your original question, you will find lots of posts on here (and maybe more on TDS) about gear and manufacturers. That will probably help you narrow in on some of the major brands to research (my personal favorites in alphabetical order are Dive Rite, OxyCheq, and Salvo).
Just remember, this is not a race and can be a very enjoyable and rewarding journey.
Have fun!
~Jeff
P.S. IF you REALLY have THAT MUCH MONEY. Then I am for sale as a dive buddy. You just need to stock up like Noah's ark -- two of everything. Oh yeah, living expenses, health benefits, and a pension.

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