H2S maybe
Where would the combustion to create CO have come from?
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Actually, one of the biggest dangers is high CO2. There have been cases in England, and Australia of high CO2 levels in air filled chambers that didn't have direct connection to the surface.
This thread reminds me of IFR flight with a cat and a duck
use an open water diver
First to fall over when the atmosphere is less than perfect.
Your sensibilities are shaken by the slightest defect.
You live your life like a canary in coal mine.
I say any small bird will do.
So this is the situation we will dive about 7000ft and come up in a very large dry cave, we then need to climb up a big breakdown pile and down the other side to get back in the water and continue exploring, Forrest being an experienced sump diver what would you do?
Don't worry Phil, I will be the Guinea pig. We can take a lighter.
I have yet to find a chamber after a sump that had air so bad it would kill without warning. I hold the reg close to my mouth and sniff the air. If it doesn't smell , or taste right, I go back on the reg. High CO2 will cause you to feel anxious, and tire easily. Low O2 in more subtle, if you feel faint, get back on the reg fast. You don't have long if the oxygen is too low.